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81.
Dr. Martin Pichette Drapeau Prof. Dr. Lukas J. Gooßen 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(52):18654-18677
The selective transformation of C?H bonds is one of the most desirable approaches to creating complexity from simple building blocks. Several directing groups are efficient in controlling the regioselectivity of catalytic C?H bond functionalizations. Among them, carboxylic acids are particularly advantageous, since they are widely available in great structural diversity and at low cost. The carboxylate directing groups can be tracelessly cleaved or may serve as the anchor point for further functionalization through decarboxylative couplings. This Minireview summarizes the substantial progress made in the last few years in the development of reactions in which carboxylate groups direct C?H bond functionalizations with formation of C?C, C?O, C?N, or C?halogen bonds at specific positions. It is divided into sections on C?C, C?O, C?N, and C?halogen bond formation, each of which is subdivided by reactions and product classes. Particular emphasis is placed on methods that enable multiple derivatizations by combining carboxylate‐directed C?H functionalization with decarboxylative couplings. 相似文献
82.
Roman Tkachov Lukas Stepien Aljoscha Roch Hartmut Komber Felix Hennersdorf Jan J. Weigand Ingmar Bauer Anton Kiriy Christoph Leyens 《Tetrahedron》2017,73(16):2250-2254
Herein, aiming at optimization of the polymerization process leading to a family of hole- and electron-conducting 1,1,2,2-ethenetetrathiolate-based polymers, such as poly(nickel-1,1,2,2-ethenetetrathiolate), poly[Kx(Ni-ett)], we investigated transformations of the monomer precursor 1,3,4,6-tetrathiapentalene-2,5-dione (TPD) occurring under polymerization conditions. We found that only one ring of TPD opens upon its reaction with potassium methoxide under inert conditions at room temperature which leads to the formation of potassium 2-oxo-1,3-dithiol-4,5-dithiolate (K2[3]). Heating of K2[3] under reflux in methanol solution under inert conditions opens the second ring, however the resulting product is not potassium ethenetetrathiolate (K4[2]), the product of an exhaustive methanolysis of TPD, but potassium tetrathiooxalate (K2[4]), the product of the decarbonylation of K2[3]. Preliminary experiments reveal that the involvement of K2[4] in the polymerization process is beneficial for reproducible formation of high quality 1,1,2,2-ethenetetrathiolate-based polymers suitable for thermoelectric applications. 相似文献
83.
Jessica E. Waters Georg Berger Dr. Andrew J. Peel Dr. Raúl García-Rodríguez Dr. Andrew D. Bond Prof. Dominic S. Wright 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(47):12036-12040
Supramolecular main group chemistry is a developing field which parallels the conventional domain of metallo-organic chemistry. Little explored building blocks in this area are main group metal-based ligands which have the appropriate donor symmetry to build desired molecular or extended arrangements. Tris(pyridyl) main group ligands (E(py)3, E=main group metal) are potentially highly versatile building blocks since shifting the N-donor arms from the 2- to the 3-positions and 4-positions provides a very simple way of changing the ligand character from mononuclear/chelating to multidentate/metal-bridging. Here, the coordination behaviour of the first main group metal tris(4-pyridyl) ligands, E(4-py)3 (E=Sb, Bi, Ph−Sn) is explored, as well as their ability to build metal-organic frameworks (MOFs). The complicated topology of these MOFs shows a marked influence on the counter anion and on the ability of the E(4-py)3 ligands to switch coordination mode, depending on the steric and donor character of the bridgehead. This structure-directing influence of the bridgehead provides a potential building strategy for future molecular and MOF design in this area. 相似文献
84.
Impinging jets over liquid surfaces are a common practice in the metallurgy and chemical industries. This paper presents a numerical study of the fluid dynamics involved in this kind of processes. URANS simulations are performed using the volume of fluid (VOF) method to deal with the multiphase physics. This unsteady approach with the appropriate computational domain allows resolution of the big eddies responsible for the low frequency phenomena. The solver we used is based on the finite volume method and turbulence is modelled with the realisable k-? model. Two different configurations belonging to the dimpling and splashing modes are under consideration. The results are compared with PIV and LeDaR experimental data previously obtained by the authors. Attention is focused on the surroundings of the impingement, where the interaction between jet and liquid film is much stronger. Finally, frequency analysis is carried out to study the flapping motion of the jet and cavity oscillations. 相似文献
85.
William K. Bell Brandon M. Rawlings Brian K. Long R. Chad Webb B. Keith Keitz Lukas Häußling C. Grant Willson 《Journal of polymer science. Part A, Polymer chemistry》2014,52(19):2769-2775
A series of photocrosslinkable polymers bearing hyperpolarizable side chain chromophores was synthesized, poled and evaluated on the basis of the thermal stability of Second Harmonic Generation (SHG). Photoinitiation allowed for control of the onset of curing. Crosslinking was monitored by infrared spectroscopy and optimal conversion was achieved by applying a slow temperature ramp during exposure. The ultimate stability of the poled polymers was directly related to the number of crosslinking substituents that were attached to the chromophore pendant group. With two reactive groups per chromophore significant SHG was retained at temperatures above the initial polymer glass transition temperature. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014 , 52, 2769–2775 相似文献
86.
Xu‐Wen Li Alexandre Ear Lukas Roger Dr. Nassima Riache Alexandre Deville Dr. Bastien Nay 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(48):16389-16393
A bio‐inspired strategy was used to complete the formal synthesis of the antitubercular hirsutellone B and congeners A and C, through construction of its decahydrofluorene core from a linear polyene strand activated at both ends by a silyl enol ether and an allyl acetate. Our synthesis features a key electrophilic cyclization, starting with the remote activation (by [Yb(OTf)3] or BF3 ? OEt2) of the allyl acetate and stereoselectively affording the C ring. This was followed by an intramolecular Diels–Alder reaction to get the tricyclic core of the natural product. The stereoselective reduction of the resulting ketone towards the formal intermediate was critical to the success of this strategy. 相似文献
87.
88.
2-Aminotetrahydropyrimidines were synthesised on solid-phase via a guanidinium intermediate and subsequent displacement of the tosylate by an imine. 相似文献
89.
90.
Lukas Lohmeyer Dr. Elisabeth Kaifer Prof. Hubert Wadepohl Prof. Hans-Jörg Himmel 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(26):5834-5845
New redox-active 1,2,5,6-tetrakis(guanidino)-naphthalene compounds, isolable and storable in the neutral and deep-green dicationic redox states and oxidisable further in two one-electron steps to the tetracations, are reported. Protonation switches on blue fluorescence, with the fluorescence intensity (quantum yield) increasing with the degree of protonation. Reactions with N-halogenosuccinimides or N-halogenophthalimides led to a series of new redox-active halogeno- and succinimido-/phthalimido-substituted derivatives. These highly selective reactions are proposed to proceed via the tri- or tetracationic state as the intermediate. The derivatives are oxidised reversibly at slightly higher potentials than that of the unsubstituted compounds to dications and further to tri- and tetracations. The integration of redox-active ligands in the transition-metal complexes shifts the redox potentials to higher values and also allows reversible oxidation in two potentially separated one-electron steps. 相似文献